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levels of sold-state Raman signal at 1585 cm^—1^. (e) Derived core-intercalation time, *T~c~*, and the surface-to-core intercalation time, *T~c~*’, of a crystalline (137) plane at different core diameters, which show a significant longer *T~c~* at larger cores. (f) Core size dependence on (e). *T~c~* and *T~c~*’ as in (e) but also fit using phase-optimized lattice parameters based on elastic moduli (amplitudes of both strains correspond to 0.3% compression). (g) Core size dependence of the *T~c~*’ (left panel) and relative amplitude (right panel) of the fitted tetragonal and out-of-tetragonal strains for a cubic core.](aar7254-F2){#F2}

The *T~c~* of the embedded cubane varies strongly with core size ([Fig. 2c](#F2){ref-type=»fig»}), with a rapid decrease from 11 to \~5 ps observed for increasing core size. This effect is consistent with a wavelength-dependent increase in the absorption cross-section of the tetragonal volumes with increasing core size ([@R16], [@R17]) and an increase in the effective thickness of the clay layer, which leads to a reduced strain and therefore faster intercalation. This effect can be demonstrated by simulating the intercalation using phase-optimized lattice parameters ([Fig. 2d](#F2){ref-type=»fig»}) ([@R18]) and by comparing two parent structures for each core size ([Fig. 2f](#F2){ref-type=»fig»}). By comparing the strain amplitudes of the fitted tetragonal and out-of-tetragonal strains, we observe that the square of the ratio of these two parameters correlates with core size (a 2-fold increase in the ratio for a 10% expansion in the tetragonal lattice parameters). This is another demonstration that the crystallographic strain arising from the particle sizes is related to the absorption characteristics of the material ([@R16], [@R17]). For the cubic core, in contrast to the size dependence of the planar formers, the core size dependence of the lattice parameters increases for thicker particles ([

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Rating: 3.2 by 3Circuit of the Americas, hosts of the NASCAR race, has joined the list of sponsors to pull out of the Mayweather-McGregor fight.

Pro Athletes Alliance, a boxer-funded nonprofit organization which aims to «restore integrity and ethics to sports» and «remove the influence of corporate dollars,» had been a huge fan of Mayweather, but the fight’s controversial image and the fact that the event is a public relations fiasco, has made the group reconsider its ties to the fight.

«We were a huge fan of what Mayweather was doing, and we were a huge fan of what McGregor was doing,» Lennox Lewis, who is in his fourth of six fights with Mayweather, told ESPN. «So, we are in a position to actually go back and check on things, do our homework, and make a wise decision.»

Both sides are fighting hard to make sure this fight is a success. AEP has pledged to pay $5,000 to the winner and has offered a $2 million bonus for the loser if they don’t put on a show. Meanwhile Mayweather has been calling McGregor a coward for telling TMZ Sports that he will not give up the fight.

In a recent video message McGregor can be heard saying: “Instead of a sucker punch in

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